Tetrafluoro-p-Benzoquinone Radicals: Chemical Exchange as Evidenced by Cidep

M. T. Craw Department of Chemistry, Queen's University, Kingston, Ontario, Canada, K7L 3N6

M. C. Depew Department of Chemistry, Queen's University, Kingston, Ontario, Canada, K7L 3N6

J. K. S. Wan Department of Chemistry, Queen's University, Kingston, Ontario, Canada, K7L 3N6

Abstract

The CIDEP characteristics of radicals derived from tetra-fluoro-p-benzoquinone have been studied. An alternating linewidth effect in the time-resolved CIDEP spectra was observed when a hydroxylic/non hydroxylic solvent mixture was used. The results are discussed in terms of chemical exchange between the neutral and anionic quinone radicals.

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Tetrafluoro-p-Benzoquinone Radicals: Chemical Exchange as Evidenced by Cidep

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Tetrafluoro-p-Benzoquinone Radicals: Chemical Exchange as Evidenced by Cidep

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