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Spectroscopy Letters
An International Journal for Rapid Communication
Volume 24, 1991 - Issue 7-8
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Original Articles

Cartesian Dynamics of Simple Molecules VIII planar quadratomics (D3h symmetry)

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Pages 959-973 | Received 15 Apr 1991, Accepted 21 May 1991, Published online: 23 Sep 2006
 

Abstract

The vibrations of planar A3B type molecules with D3h symmetry are analysed, by treating these molecules as a special case of A2BC types with C2v symmetry. Analytical expressions for the four normal mode frequencies are derived in terms of four force constants, and optimized values of the latter for the boron trihalides and sulphur trioxide are obtained and briefly discussed. Frequencies of various isotopic species are also calculated.

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