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Abstract
Normal coordinate analysis was carried out on the vapor phase Raman and i.r. spectral data of methanol and its deuterated species to determine a vibrational force field. Based on the results of calculations, the 25-parameter molecular force field was analyzed and compared with the earlier studies and the vibrational band assignments were discussed in terms of the vibrational mode mixings, particularly, in the wavenumber region below 1500 cm−1.