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Spectroscopy Letters
An International Journal for Rapid Communication
Volume 27, 1994 - Issue 4
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Original Articles

Conformational Analysis of the Aqueous β-Cyclodextrin/Barbitone Sodium Complex

Xue-Mei Wang Department of Chemistry, Nanjing University, Nanjing, 210008, P. R. China
,
Hong-Yuan Chen Department of Chemistry, Nanjing University, Nanjing, 210008, P. R. China
,
Sheng-Yong Li Lab. of Advanced Spectroscopy, Nanjing University of Science & Technology, Nanjing, 210014, P. R. China
&
Jun-De Wang Lab. of Advanced Spectroscopy, Nanjing University of Science & Technology, Nanjing, 210014, P. R. China
Pages 499-502 | Received 05 Jan 1994, Accepted 07 Feb 1994, Published online: 23 Aug 2006
 
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Abstract

The conformation of the inclusion complexes between barbitone sodium and β-cyclodextrin (β-CD) has been specifically investigated by nuclear magnetic resonance (NMR) spectrometry. It appears that the presence of the nitrogen heteroatoms within the barbiturate ring and the space-regulatory role of the side-chains contribute to the relatively weak complexes formed.

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