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Spectroscopy Letters
An International Journal for Rapid Communication
Volume 28, 1995 - Issue 3
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Original Articles

Structural Chemistry of Some Imidazole Complexes

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Pages 489-501 | Received 30 Sep 1994, Accepted 11 Nov 1994, Published online: 23 Sep 2006
 

Abstract

Synthesis of benzimidazole and 4 (Imidazole 1-yl) acetophenone complexes derived from cobalt(II), nickel(II), copper(II), palladium(II) and platinum(IV) salts were carried out. The elemental analyses suggest the formation of 1:2 and 1:4 stoichiometries (M:L). Electronic spectra and magnetic susceptibility measurements are used to infer the structures. The i.r. spectra of the ligands and their complexes are used to identify the type of bonding. Thermal analysis and electrical conductivity measurements were investigated in the temperature range 30–250°C. The results indicate slight semiconducting properties.

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