The First Heteronuclear Terbium-Zinc Cryptate—An Electrospray Mass Spectrometry Investigation

Chang-Jian Feng Coordination Chemistry State Key Laboratory, Nanjing University, Nanjing, 210093, P. R China; State Key Lab of Rare Earth Materials Chemistry and Applications, Beijing University, Beijing, 100087, P. R. China

Zhi-Quan Pan Coordination Chemistry State Key Laboratory, Nanjing University, Nanjing, 210093, P. R China

Zhi-Ling Wang Coordination Chemistry State Key Laboratory, Nanjing University, Nanjing, 210093, P. R China

Qiu-Yun Chen Coordination Chemistry State Key Laboratory, Nanjing University, Nanjing, 210093, P. R China

Qin-Hui Luo Coordination Chemistry State Key Laboratory, Nanjing University, Nanjing, 210093, P. R China; State Key Lab of Rare Earth Materials Chemistry and Applications, Beijing University, Beijing, 100087, P. R. China

Abstract

Electrospray mass spectrometry (ESMS) is described for heteronuclear terbium-zinc cryptate derived from tris(2-aminoethyl)amine (tren) and 2,6-diformyl-4-t-Butyl-phenol. The mass spectral data were compared with those of corresponded mononuclear terbium cryptate to verify the co-existence of zinc in the cryptate through isotope distribution calculation. This is the first heteronuclear cryptate studied by using ESMS.

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The First Heteronuclear Terbium-Zinc Cryptate—An Electrospray Mass Spectrometry Investigation

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The First Heteronuclear Terbium-Zinc Cryptate—An Electrospray Mass Spectrometry Investigation

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