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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 15
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Original Articles

Ytterbium Trichloride-Catalyzed Diels-Alder Reactions of Unactivated Dienes

Xinggao Fang Chemical Science and Technology (CST) Division, Los Alamos National Laboratory, Los Alamos, NM, 87545
,
Benjamin P. Warner Chemical Science and Technology (CST) Division, Los Alamos National Laboratory, Los Alamos, NM, 87545
&
John G. Watkin Chemical Science and Technology (CST) Division, Los Alamos National Laboratory, Los Alamos, NM, 87545
Pages 2669-2676 | Received 20 Oct 1999, Published online: 16 Feb 2011
 
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Abstract

Ytterbium chloride (YbCl3) is an effective and reusable catalyst for Diels-Alder reactions of unactivated dienes with α,β-unsaturated ketones and aldehydes at room temperature, leading to products with high regio- and stereoselectivities.

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