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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 20
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Original Articles

Reaction of Alkynes with Tetracarbonyl[Methoxy(2,4-Dimethoxyphenyl)Carbene]chromium: A Formal Synthesis of 7-Methoxyeleutherin

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Pages 3775-3784 | Received 23 Jan 2000, Published online: 04 Dec 2007
 

Abstract

The reaction of alkynes with tetracarbonyl[methoxy(2,4-dimethoxyphenyl)carbene]-chromium, followed by oxidation, gives naphthoquinones as well as other cyclized products. This has been utilized in the preparation of (3) an intermediate in the synthesis of 7-methoxyeleutherin.

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