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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 6
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Original Articles

Cyclotrimerization of Nitriles Catalyzed by SmI2/Amines: Synthesis of 2,4,6-Trisubstituted-S-Triazines

Fan Xu Department of Chemistry, Suzhou University, Suzhou, Jiangsu, 215006, China
,
Jian-Hua Sun Department of Chemistry, Suzhou University, Suzhou, Jiangsu, 215006, China
,
Hai-Bin Yan Department of Chemistry, Suzhou University, Suzhou, Jiangsu, 215006, China
&
Qi Shen Department of Chemistry, Suzhou University, Suzhou, Jiangsu, 215006, China
Pages 1017-1022 | Received 26 Apr 1999, Published online: 04 Dec 2007
 
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Abstract

SmI2 has been found to catalyze a reaction of cyclotrimerization of nitriles in the presence of amine as cocatalyst to give 2,4,6-trisubstituted-s-triazines effectively under mild reaction conditions. The yield depends on the structure of nitriles.

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