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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 6
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Original Articles

Asymmetric Aziridination by Reaction of Chiral Sulfinimine Derived From (+)-Camphor with Dimethyloxosulfonium Methylide

Wei Zhu Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041, P. R. China
,
Yan Li Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041, P. R. China
,
Zhiyong Chen Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041, P. R. China
,
Di Li Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041, P. R. China
&
Guishu Yang Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041, P. R. China
Pages 1075-1081 | Received 23 Mar 1999, Published online: 04 Dec 2007
 
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Abstract

Addition of dimethyloxosulfonium methylide to chiral nonracemic pure (+)-camphor-derived sulfinimine I affords N-sulfinyl aziridine. which are easily separated The N-(+)-camphor-based-sulfinyl auxiliary was removed without ring opening by treatment with MeLi.

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