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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 6
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Original Articles

Novel Synthesis of Haloaromatic Tertiary Alcohols Using (η6-Fluoroarene)tricarbonylchromium(0) Complexes

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Pages 1115-1137 | Received 25 May 1999, Published online: 04 Dec 2007
 

Abstract

Regioselective synthesis of haloaromatic tertiary alcohols can be achieved by ortho deprotonation/electrophilic reactions of (η6- fluoroarene)Cr(CO)3 complexes with halobenzophenones and metal removal. The coexistence of different halogens in the aromatic rings of these molecules make them unique within the group of tertiary alcohols.

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