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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 7
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Original Articles

A new and Facile Method for Synthesis of AZA-Wittig Reagents under Microwave Irradiation

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Pages 1287-1294 | Received 09 Aug 1999, Published online: 04 Dec 2007
 

Abstract

We report a simple and quick synthetic method of some new Aza-Wittig reagents in anhydrous acetonitrile under microwave irradiation. 1-Substituted aryl-4-ethoxycarbonyl-5-[(triphenylphosphoranylidene)amino]-1, 2, 3-triazoles can be obtained within three minutes by microwave irradiation to the mixture of 1-substituted aryl-4-ethoxycarbonyl-5-amino-1,2,3-triazoles, triphenylphosphine, hexachloroethane and triethylamine. The products were characteried by IR, NMR, MS methods and elemental analysis.

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