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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 10
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Original Articles

Synthesis of Allyl-Type Selenides and α-Selenoesters in Aqueous Media Promoted by Cadmium

Yunfa Zheng Li Shut Teacher's College, Zhejiang, 323000, China
,
Weiliang Bao Department of Chemistry, Zhejiang University Xi Xi Campus, Hangzhou, 310028, China
&
Yongmin Zhang Department of Chemistry, Zhejiang University Xi Xi Campus, Hangzhou, 310028, China
Pages 1731-1736 | Accepted 01 Aug 1999, Published online: 04 Dec 2007
 
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Abstract

Promoted by metallic cadmium which was produced by reduction of CdCl2 H2O with samarium in situ, allyl bromide and α-bromocarboxylates react with diorgano diselenides in aqueous solutions to give allylic-type selenides and α-selenocarboxylates in moderate to good yields.

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