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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 10
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Original Articles

An Improved Synthesis of Dialkylcyclopropenones

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Pages 1767-1777 | Accepted 27 Aug 1999, Published online: 04 Dec 2007
 

Abstract

Dialkylcyclopropenones are formed in high yields when alkynes are treated with chloroform-butyllithium in THF at - 78 °C followed by acidic hydrolysis of the dichlorocyclopropene intermediates at low temperatures.

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