Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 35, 2005 - Issue 20
Submit an article Journal homepage
164
Views
11
CrossRef citations to date
0
Altmetric
Original Articles

Sulfur‐Containing Chiral Bis(oxazolines) Tested in Copper‐Catalyzed Asymmetric Cyclopropanation

Ming Zhang Gao Department of Chemistry, Texas A&M University, College Station, Texas, USA
,
Bo Wang School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou, China
,
Deyuan Kong Department of Chemistry, Texas A&M University, College Station, Texas, USA
,
Ralph A. Zingaro Department of Chemistry, Texas A&M University, College Station, Texas, USA
,
Abraham Clearfield Department of Chemistry, Texas A&M University, College Station, Texas, USACorrespondence[email protected]
&
Zun Le Xu School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou, China
Pages 2665-2673 | Received 18 May 2005, Published online: 22 Aug 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

The novel C2‐symmetric sulfur‐containing chiral bis(oxazoline) compound has been synthesized and characterized by X‐ray crystallography. Highly enantioselective and diastereoselective cyclopropanation reactions have been performed using the copper‐bis(oxazoline) catalyst.

Acknowledgments

The authors acknowledge the assistance of the Robert A. Welch Foundation (A‐084) and the Department of Energy, Basic Sciences Division (DE‐FG03‐00ER 15806), for financial support.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Asymmetric cyclopropanation catalyzed by C2-symmetric bi(oxazolines)
Source: Elsevier BV
Highly Enantioselective Cyclopropanation of Styrenes with Diazoacetates Catalyzed by Optically Active β-Ketoiminato Cobalt(II) Complexes
Source: The Chemical Society of Japan
Synthesis of Chiral 2,5-Bis(oxazolinyl)thiophenes and Their Application as Chiral Shift Reagents for 1,1′-Bi-2-naphthol
Source: Wiley
Synthesis of New Sulfur-Containing Oxazoline Ligands and Their Use in Palladium-Catalyzed Allylic Substitution.
Source: Wiley
Chiral ferrocenyl-oxazolines incorporating thioether units: effective ligands for palladium-catalysed allylic substitution
Source: Elsevier BV
Asymmetric induction in carbenoid reaction by means of a dissymmetric copper chelate
Source: Elsevier BV
New Chiral Ruthenium bis(Oxazolinyl)Pyridine Catalyst - Efficient Asymmetric Cyclopropanation of Olefins with Diazoacetates
Source: American Chemical Society (ACS)
Bis(oxazolines) as chiral ligands in metal-catalyzed asymmetric reactions. Catalytic, asymmetric cyclopropanation of olefins
Source: American Chemical Society (ACS)
Asymmetric synthesis of permethric acid. stereochemistry of chiral copper carbenoid reaction
Source: Elsevier BV
Homogeneous catalysis in the decomposition of diazo compounds by copper chelates
Source: Elsevier BV
Synthesis of homochiral bis (oxazolinyl) pyridine type ligands for asymmetric cyclopropanation reactions
Source: Elsevier BV
Ojima/Asymmetric Synthesis
Source: John Wiley & Sons, Inc.
Chiral Ruthenium(II)-Bis(2-oxazolin-2-yl)pyridine Complexes. Asymmetric Catalytic Cyclopropanation of Olefins and Diazoacetates.
Source: The Chemical Society of Japan
Catalytic and asymmetric cyclopropanation of styrenes catalysed by ruthenium porphyrin and porphycene complexes
Source: Royal Society of Chemistry (RSC)
Asymmetric synthesis of chrysanthemic acid. An application of copper carbenoid reaction
Source: Elsevier BV
Highly enantioselective cyclopropanation of styrene derivatives using Co(III)-salen complex as a catalyst
Source: Elsevier BV
Asymmetric Cyclopropanations by Rhodium(II) N-(Arylsulfonyl)prolinate Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Alkenes. Practical Enantioselective Synthesis of the Four Stereoisomers of 2-Phenylcyclopropan-1-amino Acid
Source: American Chemical Society (ACS)
Enantioselective Indole Friedel−Crafts Alkylations Catalyzed by Bis(oxazolinyl)pyridine−Scandium(III) Triflate Complexes
Source: American Chemical Society (ACS)
CCDC 232494: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Soluble polymer-supported ruthenium porphyrin catalysts for epoxidation, cyclopropanation, and aziridination of alkenes.
Source: American Chemical Society (ACS)
Synthesis of chiral bis(oxazolinyl)biferrocene ligands and their application to Cu(I)-catalyzed asymmetric cyclopropanation
Source: Elsevier BV

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.