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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 6
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Original Articles

Zirconium(IV) Chloride–Mediated Chemoselective Conjugate Addition of Aliphatic Amines to α,β‐Ethylenic Compounds

, , , &
Pages 795-801 | Received 01 Sep 2005, Published online: 16 Aug 2006
 

Abstract

Zirconium chloride efficiently catalyzes the conjugate addition of a variety of aliphatic amines to α,β‐unsaturated ester, nitriles, and ketones to give the corresponding β‐amino derivatives in excellent yields under mild reaction conditions. Aromatic amines do not participate in this transformation.

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