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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 20
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Original Articles

Superoxide‐Mediated Regioselective Deblocking of the Tosyl Group from N‐Tosylcarboxamides

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Pages 3075-3078 | Received 08 Feb 2006, Published online: 16 Feb 2007
 

Abstract

In situ–generated tetraethylammonium superoxide brings about an easy and selective cleavage of the N[sbnd]S bond of N‐tosylcarboxamides, providing a new method for the deblocking of the tosyl group from such substrates.

Acknowledgment

The authors thank Council of Scientific and Industrial Research (CSIR), New Delhi, for financial support.

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