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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 17
288
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Original Articles

Research on the Cyanosilylation of Prochiral Aldehydes Catalyzed by Alkyldimethoxyl Silylene–Bridged Lanthanide Complexes

, , , , &
Pages 2483-2490 | Received 19 Dec 2005, Published online: 27 Oct 2006
 

Abstract

A series of novel silylene‐bridged Ln‐O rare earth complexes are very efficient Lewis acidic catalysts in cyanosilylation of aldehydes, giving some cyano trimethylsilyl ethers of aldehydes in >99% yields.

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