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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 17
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Original Articles

Oxidation of Benzylic Alcohols to Their Corresponding Carbonyl Compounds using KIO4 in Ionic Liquid by Microwave Irradiation

Abdol Reza Hajipour Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan, IranCorrespondence[email protected]
,
Fatemeh Rafiee Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan, Iran
&
Arnold E. Ruoho Department of Pharmacology, University of Wisconsin Medical School, Madison, Wisconsin, USA
Pages 2563-2568 | Received 02 Feb 2006, Published online: 27 Oct 2006
 
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Abstract

A chemoselective, straightforward, and rapid method for oxidation of alcohols to the corresponding carbonyl compounds using microwave irradiation and a catalytic amount of ionic liquid is reported. The reaction has been carried out with excellent yields and short reaction times.

Acknowledgments

We gratefully acknowledge the funding support received for this project from the Isfahan University of Technology (IUT), I.R. Iran (A. R. H.), and Grants GM 033138, MH 065503, and NS 033650 (A. E. R.) from the National Institutes of Health. USA. Further financial support from Center of Excellency in Chemistry Research (IUT) is gratefully acknowledged.

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