Regio‐ and Diastereoselective Ring‐Opening Reaction of Epoxides with Nitric Oxide

Yuan Fan State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, Gansu, China

Xiaojie Shang State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, Gansu, China

Zhongquan Liu State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, Gansu, China; Academy of Organic Chemistry, GanNan Teachers' College, Ganzhou, Jiangxi, China

Longmin Wu State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, Gansu, ChinaCorrespondence[email protected]

Abstract

Ring‐opening reactions of epoxides with nitric oxide afforded syn or anti α‐hydroxy nitrates in high regio‐ and diastereoselectivities in good yields.

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Acknowledgment

We thank the National Natural Science Foundation of China (Grant No. 20272022) for financial support.

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Regio‐ and Diastereoselective Ring‐Opening Reaction of Epoxides with Nitric Oxide

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Regio‐ and Diastereoselective Ring‐Opening Reaction of Epoxides with Nitric Oxide

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