Synthesis of Ketones from Acyl Chlorides and Triorganoindium Reagents by Pd‐Catalyzed Cross‐Coupling

C. Croix CEA Le Ripault, Materials Department, Monts, France

A. Balland‐Longeau CEA Le Ripault, Materials Department, Monts, France

A. Duchêne Laboratoire de Synthèse et Physicochimie Organique et Thérapeutique, Faculté des Sciences de Tours, Parc de Grandmont, Tours, France

J. Thibonnet Laboratoire de Synthèse et Physicochimie Organique et Thérapeutique, Faculté des Sciences de Tours, Parc de Grandmont, Tours, FranceCorrespondence[email protected]

Abstract

Triorganoindium reagents prepared from indium tribromide and 3 equiv of organolithium reagents react with acyl chlorides in palladium‐catalyzed cross‐coupling for preparation of new ketones.

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Acknowledgments

We thank CEA Le Ripault for providing financial support and characterization.

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Synthesis of Ketones from Acyl Chlorides and Triorganoindium Reagents by Pd‐Catalyzed Cross‐Coupling

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Synthesis of Ketones from Acyl Chlorides and Triorganoindium Reagents by Pd‐Catalyzed Cross‐Coupling

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