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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 37, 2007 - Issue 7
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Original Articles

Solvent‐Free Chemoselective Synthesis of 1,1‐Diacetates Catalyzed by Cu(NO3)2 · 3H2O

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Pages 1121-1126 | Received 06 Jun 2006, Published online: 13 Oct 2010
 

Abstract

1,1‐Diacetates have been synthesized by the reaction of a variety of aldehydes with acetic anhydride in the presence of cupric nitrate as catalyst under solvent‐free conditions. Ketones were not converted to the corresponding diacetates under these conditions.

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