Sm/HOAc/EtOH System–Mediated Reduction of Baylis–Hillman Acetates

Yunkui Liu State Key Laboratory Breeding Base of Green Chemistry—Synthesis Technology, Zhejiang University of Technology, Hangzhou, China

Dajie Mao State Key Laboratory Breeding Base of Green Chemistry—Synthesis Technology, Zhejiang University of Technology, Hangzhou, China

Danqian Xu State Key Laboratory Breeding Base of Green Chemistry—Synthesis Technology, Zhejiang University of Technology, Hangzhou, China

Zhenyuan Xu State Key Laboratory Breeding Base of Green Chemistry—Synthesis Technology, Zhejiang University of Technology, Hangzhou, ChinaCorrespondence[email protected]

Yongmin Zhang Department of Chemistry, Zhejiang University, Hangzhou, China

Abstract

Selective formation of (2E)‐2‐methylalk‐2‐enoates or 2‐methyl alkanoates could be achieved in moderate to good yields under mild conditions via Sm/HOAc/EtOH system–mediated reduction of Baylis–Hillman acetates depending on the amount of samarium consumed in the reactions.

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Acknowledgment

The authors are grateful to the Opening Foundation of Zhejiang Provincial Top Key Discipline for financial support.

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Sm/HOAc/EtOH System–Mediated Reduction of Baylis–Hillman Acetates

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Sm/HOAc/EtOH System–Mediated Reduction of Baylis–Hillman Acetates

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