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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 38, 2008 - Issue 5
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Original Articles

C‐Vinylation of 1,8‐Dihydroxyanthraquinone Promoted by Triphenylphosphine

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Pages 703-712 | Received 08 Aug 2007, Published online: 15 Feb 2008
 

Abstract

The reaction of dialkyl acetylendicarboxylates with 1,8‐dihydroxyanthraquinone in the presence of triphenylphosphine (20 mol%) produces dialkyl (E)‐2‐(1,8‐dihydroxy‐9,10‐dioxo‐9,10‐dihydro‐2‐anthracenyl)‐2‐butenedioates in good yields. When the reaction is performed in the presence of 2.2 equivalents of the acetylenic ester, a nearly 2:1 mixture of dialkyl (E)‐2‐{1,8‐dihydroxy‐7‐[(E)‐3‐methoxy‐1‐(methoxycarbonyl)‐3‐oxo‐1‐propenyl]‐9,10‐dioxo‐9,10‐dihydro‐2‐anthracenyl}‐2‐butenedioates and dialkyl (Z)‐2‐{1,8‐dihydroxy‐7‐[(E)‐3‐methoxy‐1‐(methoxycarbonyl)‐3‐oxo‐1‐propenyl]‐9,10‐dioxo‐9,10‐dihydro‐2‐anthracenyl}‐2‐butenedioates is obtained.

Acknowledgments

We are grateful to the Institute for Colorants, Paint, and Coatings and Tarbiat Modares University for financial support.

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