FeCl₃‐Catalyzed Nucleophilic Substitution of Baylis–Hillman Adducts with Alcohols

Xueshun Jia Department of Chemistry, Shanghai University, Shanghai, ChinaCorrespondence[email protected]

Peichao Zhao Department of Chemistry, Shanghai University, Shanghai, China

Xiaotao Liu Department of Chemistry, Shanghai University, Shanghai, China

Jian Li Department of Chemistry, Shanghai University, Shanghai, China

Abstract

FeCl₃‐catalyzed nucleophilic substitution reaction of Baylis–Hillman adducts with alcohols is described. The present protocol allows for the efficient syntheses of many kinds of functional ethers. This conversion is also a green route because water is the only side product.

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Acknowledgment

We thank the National Natural Science Foundation of China (Nos. 20472048 and 20572068) for support of this work.

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FeCl₃‐Catalyzed Nucleophilic Substitution of Baylis–Hillman Adducts with Alcohols

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FeCl3‐Catalyzed Nucleophilic Substitution of Baylis–Hillman Adducts with Alcohols

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FeCl₃‐Catalyzed Nucleophilic Substitution of Baylis–Hillman Adducts with Alcohols