Stereoselective Synthesis of Functionalized 1,4-Dienes

Sonia Khamri Laboratoire de Chimie Organique et Organométallique, Université de Tunis El Manar, Faculté des Sciences, Tunis, Tunisia

Taoufik Turki Laboratoire de Chimie Organique et Organométallique, Université de Tunis El Manar, Faculté des Sciences, Tunis, Tunisia

Hassen Amri Laboratoire de Chimie Organique et Organométallique, Université de Tunis El Manar, Faculté des Sciences, Tunis, TunisiaCorrespondence[email protected]

Abstract

The article reports a stereoselective synthesis of functionalized 1,4-dienes 5, 6 by coupling allylic Baylis–Hillman acetates 1 and vinyl magnesium chloride at low temperature and in the presence of a catalytic amount of LiCuBr₂ (3%).

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Stereoselective Synthesis of Functionalized 1,4-Dienes

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Stereoselective Synthesis of Functionalized 1,4-Dienes

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