The Reaction of Electron-Deficient Cyclopropane Derivatives with Aromatic Amines

Yali Chen Department of Chemistry, Shanghai University, Shanghai, ChinaCorrespondence[email protected]

Weiguo Cao Department of Chemistry, Shanghai University, Shanghai, China; State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai, China

Meifei Yuan Department of Chemistry, Shanghai University, Shanghai, China

Huihui Wang Department of Chemistry, Shanghai University, Shanghai, China

Weiyu Ding Department of Chemistry, Shanghai University, Shanghai, China

Min Shao Department of Chemistry, Shanghai University, Shanghai, China

Xiangming Xu DuPont Agricultural Chemicals Ltd., Shanghai, China

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Abstract

N-Aryl-trans,trans-α-carboxyl-β-benzoyl-γ-aryl-γ-butyrolactams were synthesized in high yields with high stereoselectivity by the reaction of electron-deficient cyclopropane derivatives, cis-1-benzoyl-2-aryl-6,6-dimethyl-5,7-dioxo-spiro-[Citation2 Citation5]-4,8-octadiones, with aromatic amines. The reaction mechanism was proposed.

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ACKNOWLEDGMENT

This project was supported by the National Natural Science Foundation of China (No. 20472047) and the Foundations of Education Commission of Shanghai Municipality (Nos. J50102 and 08ZZ44).

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The Reaction of Electron-Deficient Cyclopropane Derivatives with Aromatic Amines

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The Reaction of Electron-Deficient Cyclopropane Derivatives with Aromatic Amines

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