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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 40, 2010 - Issue 7
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Original Articles

Palladium-Catalyzed Cross-Coupling of 2,3-Naphthoxadisilole with Aryl Halides

Han Ding Department of Chemistry, Shanghai University, Shanghai, China
,
Yali Chen Department of Chemistry, Shanghai University, Shanghai, ChinaCorrespondence[email protected]
,
Weiguo Cao Department of Chemistry, Shanghai University, Shanghai, China; State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai, China
,
Kaicheng Wu Department of Chemistry, Shanghai University, Shanghai, China
,
Jie Chen Department of Chemistry, Shanghai University, Shanghai, China
&
Albert W. M. Lee Department of Chemistry and Centre for Advanced Luminescence Materials, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China
Pages 984-991 | Received 02 Feb 2009, Published online: 04 Mar 2010
 
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Abstract

Palladium-catalyzed cross-coupling between 2,3-naphthoxadisilole and aryl halides in the presence of tetrabutylammonium fluoride afforded 2-aryl naphthalenes. This is first report that oxadisilole served as a partner in the palladium-catalyzed cross-coupling reactions. The reaction mechanism was also studied.

ACKNOWLEDGMENTS

Financial support from the National Natural Science Foundation of China (No. 20872086), the Project of Shanghai Municipal Education Commission (Nos. 09YZ19 and J50102), the Faculty Research Grant, and the Hong Kong Research Grants Council (HKBU 201307) are gratefully acknowledged.

Notes

a Isolated yield.

b No reaction.

a Isolated yield.

b No reaction.

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