Abstract
An aqueous aza-Michael reaction is efficiently achieved with excellent conversions without any additives. The method works very well on a molar scale with selectively for aliphatic amines. An intermediate for spermine is also made by this green process.
ACKNOWLEDGMENTS
We are grateful to Gujarat Narmada Fertilizer Corporation (Bharuch) for the financial support and to Prof. B. V. Kamath for his constant encouragement as well as providing laboratory facilities.
Notes
Notes. A, with acrylonitrile; B, with tert-butyl acrylate.