Abstract
With a view to investigate the oxidation behaviors of cetyltrimethylammonium dichromate on multifunctional groups, some arylthioureas were subjected to oxidation, both in neutral and in acidic conditions. In neutral conditions, the products were found to be a mixture of corresponding urea and isonitrile. In acidic conditions, the products were corresponding ureas only. A probable mechanism was proposed for the formation of the product, wherein the first step involves coupling of –NH2 and –SH of one molecule to the –NH2 and –SH of another molecule, respectively, which is followed by removal of nitrogen and sulfur. The microwave irradiation resulted in great yield of isonitrile than urea in neutral conditions.
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ACKNOWLEDGMENTS
B. K. M. thanks the University Grants Commission, New Delhi, for financial assistance through a research project. S. S. thanks the Council of Scientific and Industrial Research, New Delhi, for a senior research fellowship.
Notes
Note. The yields are on isolation basis.