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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 41, 2011 - Issue 14
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Original Articles

New Preparation of (Z)-1-Phenyl-3-cyano-2-propen-1-ones

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Pages 2123-2134 | Received 06 May 2010, Published online: 20 May 2011
 

Abstract

Reaction of γ-phenyl-β,γ-unsaturated hydroxamates with bis(collidine)bromine(I) hexafluorophosphate led to the formation of cyclic bromo imidates. Reaction of these with triethylamine led to the formation of 3-cyano-2-propen-1-ones with good yields by a fragmentation reaction.

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