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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 44, 2014 - Issue 16
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Original Articles

Differential Oxidation Conditions of Substituted Cyclobutanols Derived from Terpenes

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Pages 2393-2400 | Received 16 Dec 2013, Published online: 01 Jul 2014
 

Abstract

The use of different oxidants for homochiral cyclobutanols afforded dissimilar products depending on the agent used. Dess–Martin periodinane allowed us to obtain the homochiral cyclobutanones and sodium hypochlorite produced only one of the two possible regioisomeric γ-butyrolactones.

GRAPHICAL ABSTRACT

Notes

a Calculated from NMR spectra integrations.

b Isolated yield.

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