Synthetic Communications

An International Journal for Rapid Communication of Synthetic Organic Chemistry

Volume 45, 2015 - Issue 12

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Original Articles

Iodine Monochloride (ICl) as a Highly Efficient, Green Oxidant for the Oxidation of Alcohols to Corresponding Carbonyl Compounds

Peng WeiSchool of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, China;Tianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China

Datong ZhangSchool of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, ChinaCorrespondence[email protected]

Zhigang GaoSchool of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, China;Tianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China

Wenqing CaiTianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China

Weiren XuTianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China

Lida TangTianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China

Guilong ZhaoSchool of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, China;Tianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, ChinaCorrespondence[email protected]

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ABSTRACT

Iodine monochloride (ICl) was discovered to be a highly efficient, green oxidant, which can oxidize aldose hemiacetals, diarylmethanols, arylalkylmethanols, anddialkylmethanols to the corresponding aldose lactones, diarylmethanones, arylalkylmethanones, and dialkylmethanones, respectively, in high yields. ICl as a green, metal-free oxidant is characterized by mild reaction condition, short reaction time, good yield, and broad scope.

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Iodine Monochloride (ICl) as a Highly Efficient, Green Oxidant for the Oxidation of Alcohols to Corresponding Carbonyl Compounds

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Iodine Monochloride (ICl) as a Highly Efficient, Green Oxidant for the Oxidation of Alcohols to Corresponding Carbonyl Compounds

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