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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 45, 2015 - Issue 11
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Original Articles

Synthesis of Tris(ɣ-oximinoalkyl)amines, New Tripodal N4 Ligands

, , , , , , , & show all
Pages 1362-1366 | Received 21 Jan 2015, Published online: 16 Apr 2015
 

Abstract

An original approach to the synthesis of tris(γ-oximinoalkyl)amines was proposed. The suggested synthetic sequence is based on aza-Michael addition of ammonia to methyl vinyl ketone and oximation of obtained products with hydroxylamine or O-alkhylhydroxylamines. The tris(γ-oximinoalkyl)amines may be considered as prospective N4 tripodal ligands.

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SUPPORTING INFORMATION

Full experimental detail and 1H and 13C NMR spectra for this article can be accessed on the publisher’s website.

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