Synthetic Communications

An International Journal for Rapid Communication of Synthetic Organic Chemistry

Volume 48, 2018 - Issue 7

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Original Articles

Iron-catalyzed boration of allylic alcohols with H₃BO₃ as an additive

Yuhan ZhouState Key Laboratory of Fine Chemicals, School of Pharmaceutical Science and Technology, Dalian University of Technology, Dalian, P. R. ChinaCorrespondence[email protected]

http://orcid.org/0000-0002-1860-8669 View further author information

Huan WangState Key Laboratory of Fine Chemicals, School of Pharmaceutical Science and Technology, Dalian University of Technology, Dalian, P. R. China

http://orcid.org/0000-0001-5792-7841 View further author information

Yang LiuState Key Laboratory of Fine Chemicals, School of Pharmaceutical Science and Technology, Dalian University of Technology, Dalian, P. R. China

http://orcid.org/0000-0002-5860-1437 View further author information

Yilong ZhaoState Key Laboratory of Fine Chemicals, School of Pharmaceutical Science and Technology, Dalian University of Technology, Dalian, P. R. China

http://orcid.org/0000-0001-7938-8973 View further author information

Chunxia ZhangState Key Laboratory of Fine Chemicals, School of Pharmaceutical Science and Technology, Dalian University of Technology, Dalian, P. R. China

http://orcid.org/0000-0002-5197-4679 View further author information

Jingping QuState Key Laboratory of Fine Chemicals, School of Pharmaceutical Science and Technology, Dalian University of Technology, Dalian, P. R. China

http://orcid.org/0000-0002-7576-0798 View further author information

ABSTRACT

A method for the synthesis of allylboronates by iron-catalyzed boration of allylic alcohols with H₃BO₃ as an additive is developed. The introduction of H₃BO₃ promotes the cleavage of C‒O bond in allylic alcohols obviously. Functional groups, such as fluoro, chloro, bromo, alkyl, and alkoxy, are tolerated well. Thus, various allylboronates are obtained in acceptable yield.

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The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (Nos. 21576041 and 21231003) and the program for Changjiang Scholars and Innovative Research Team in University (No. IRT13008).

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Iron-catalyzed boration of allylic alcohols with H₃BO₃ as an additive

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Iron-catalyzed boration of allylic alcohols with H3BO3 as an additive

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Iron-catalyzed boration of allylic alcohols with H₃BO₃ as an additive