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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 48, 2018 - Issue 8
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Original Articles

Facial strategy for radical species through Ag(I)-mediated oxidation of the alkyl trifluoroborates

Siyi DingKey Laboratory of Organic Polymer Photoelectric Materials, School of Science, Xijing University, Xi’an, Shaanxi, ChinaORCID Iconhttp://orcid.org/0000-0001-5446-0254
ORCID Icon,
Shaopeng TianKey Laboratory of Organic Polymer Photoelectric Materials, School of Science, Xijing University, Xi’an, Shaanxi, China
,
Yuzhen ZhaoKey Laboratory of Organic Polymer Photoelectric Materials, School of Science, Xijing University, Xi’an, Shaanxi, China
,
Qiang MaKey Laboratory of Organic Polymer Photoelectric Materials, School of Science, Xijing University, Xi’an, Shaanxi, China
,
Min ZhuKey Laboratory of Organic Polymer Photoelectric Materials, School of Science, Xijing University, Xi’an, Shaanxi, China
,
Huaping RenKey Laboratory of Organic Polymer Photoelectric Materials, School of Science, Xijing University, Xi’an, Shaanxi, China
,
Kexuan LiKey Laboratory of Organic Polymer Photoelectric Materials, School of Science, Xijing University, Xi’an, Shaanxi, China
&
Zongcheng MiaoKey Laboratory of Organic Polymer Photoelectric Materials, School of Science, Xijing University, Xi’an, Shaanxi, ChinaCorrespondence[email protected]
 show all
Pages 936-945 | Received 18 Sep 2017, Published online: 09 Mar 2018
 
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ABSTRACT

A rapid and highly efficient method for the radical formation using potassium alkylfluoroborates as radical precursor is devised and developed which conducts under relatively mild condition using silver(I) oxide as the oxidant. The observed silver mirror phenomenon hints at the fact that Ag2O is the real oxidant. This approach effectively overcomes the drawbacks-stringent reaction conditions and poor tolerance of a variety of functional groups.

GRAPHICAL ABSTRACT

Funding

We are grateful for financial support by the National Science Foundation of China (No. 51673157) and Special Fund for Talent Research of Xijing University (Nos. XJ17B01 and XJ16T05). Thank Pro Pengfei Li (Xi’an Jiaotong University) very much for his guidance and advices during this work.

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