Synthetic Communications

An International Journal for Rapid Communication of Synthetic Organic Chemistry

Volume 48, 2018 - Issue 14

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Synthetic Communications Review

N-heterocyclic carbene-catalyzed regio- and stereoselective hydrothiolation reaction of alkynes

Zi-Song CongLaboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur, Autonomous Region, People’s Republic of ChinaView further author information

Yang ZhangLaboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur, Autonomous Region, People’s Republic of ChinaView further author information

Guang-Fen DuLaboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur, Autonomous Region, People’s Republic of ChinaCorrespondence[email protected]
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Cheng-Zhi GuLaboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur, Autonomous Region, People’s Republic of ChinaView further author information

Lin HeLaboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur, Autonomous Region, People’s Republic of ChinaView further author information

Abstract

N-heterocyclic carbenes (NHCs) have been utilized as Brønsted base to catalyze the hydrothiolation reaction between alkynes and thiols to produce the vinyl sulfides stereoselectively.

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This work was supported by the National Natural Science Foundation of China [No. 21662029], the Young Scientists Foundation of Shihezi University [Nos. RCZX201546, 2015ZRKXJQ05] and the Excellent Young Teachers Plan of Bingtuan [CZ027203].

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N-heterocyclic carbene-catalyzed regio- and stereoselective hydrothiolation reaction of alkynes

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N-heterocyclic carbene-catalyzed regio- and stereoselective hydrothiolation reaction of alkynes

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