http://orcid.org/0000-0003-1588-0488
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Abstract
Protocols for the synthesis of cage-substituted 1-vinylsilatranes have been developed and updated. The 1-vinylsilatranes with organic substituents attached to silatrane cage were functionalized in ruthenium-catalyzed trans-silylation with olefins, leading to novel styrylsilatranes in high yields.
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Acknowledgments
We would like to thank Maciej Zaranek, MSc, for providing us with substituted triethanolamines.
Additional information
Funding
The authors gratefully acknowledge the financial support from the National Science Centre (Narodowe Centrum Nauki, Poland) [MAESTRO project No. 2011/02A/ST5/00472].