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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 49, 2019 - Issue 24
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Synthetic Communications Reviews

A convenient synthesis of 2,5-diaroyl-4-hydroxy cyclopent-2-enones incorporating aromatic and heteroaromatic moieties

Aswathy L. BalachandranDepartment of Chemistry, University of Kerala, Thiruvananthapuram, India; View further author information
,
C. S. AthiraChemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (CSIR-NIIST), Thiruvananthapuram, IndiaView further author information
,
Ani DeepthiDepartment of Chemistry, University of Kerala, Thiruvananthapuram, India; Correspondence[email protected]
View further author information
&
E. G. JayasreeDepartment of Chemistry, University of Kerala, Thiruvananthapuram, India; View further author information
Pages 3401-3411 | Received 08 Aug 2019, Published online: 14 Oct 2019
 
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Abstract

The base-catalyzed reaction of 1,5-diphenyl-pentane-1,3,5-trione with aromatic/heteroaromatic 1,2-diones leading to the synthesis of 2,5-diaroyl-4-hydroxycyclopent-2-enones and its conversion to 2,5-diaroylcyclopentadienones is reported here. 2,5-Dibenzoyl-4-hydroxycyclopent-2-enone and 2,5-dithenoyl-4-hydroxycyclopent-2-enone are valuable compounds which act as chemosensors for selective detection of Fe3+ and Cu2+, respectively.

Graphical Abstract

Acknowledgements

All authors thank SICC, University of Kerala for NMR and spectral analysis and NIIST, Trivandrum for Mass analysis.

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

ALB thanks the UGC for Senior Research Fellowship.

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