Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 49, 2019 - Issue 24
Submit an article Journal homepage
150
Views
1
CrossRef citations to date
0
Altmetric
Synthetic Communications Reviews

Visible light-promoted self-coupling of N-chloramines at room temperature: A metal-free access to substituted amides

Narendra R. ChaubeyDepartment of Chemistry, Institute of Science, Banaras Hindu University, Varanasi, IndiaCorrespondence[email protected]
View further author information
Pages 3546-3552 | Received 02 Apr 2019, Published online: 21 Oct 2019
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

An efficient protocol to synthesize substituted amides via self-coupling of N-chlorobenzylamines has been developed under visible light-promoted mild condition. Both the electron-deficient and electron-rich benzylamines undergo self-coupling very readily to produce the amide linkage under given reaction conditions.

Graphical Abstract

Acknowledgments

Dr. Narendra R. Chaubey is thankful towards Prof. K. N. Singh, Department of Chemistry, BHU, India and UGC, New Delhi for D. S. Kothari Post-Doctoral Fellowship.

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

Dr Narendra R. Chaubey is thankful toward UGC, New Delhi, for D. S. Kothari Post-Doctoral Fellowship.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Highly selective transition-metal-free transamidation of amides and amidation of esters at room temperature
Source: Springer Nature America, Inc
Radical-Induced Metal and Solvent-Free Cross-Coupling Using TBAI–TBHP: Oxidative Amidation of Aldehydes and Alcohols with N-Chloramines via C–H Activation
Source: American Chemical Society (ACS)
“On Water” Metal-Catalyst-Free Oxidative Coupling–Amidation of Amines To Access Imines and Amides
Source: American Chemical Society (ACS)
Direct Synthesis of Amides by Dehydrogenative Coupling of Amines with either Alcohols or Esters: Manganese Pincer Complex as Catalyst
Source: Wiley
MnO2 Promoted Sequential C–O and C–N Bond Formation via C–H Activation of Methylarenes: A New Approach to Amides
Source: American Chemical Society (ACS)
Metal-Free Aerobic Oxidative C−C Bond Cleavage between the Carbonyl Carbon and the α-Carbon of α-Azido Ketones: A Novel Synthesis of N-Alkylated Benzamides
Source: Wiley
Diphenylsilane as a coupling reagent for amide bond formation
Source: Royal Society of Chemistry (RSC)
Visible light-promoted self-coupling of N-chloramines at room temperature: A metal-free access to substituted amides
Source: Taylor & Francis
Molecular-Iodine-Catalyzed Transformation of Benzyl Amines to N -Benzyl Benzamides via Oxidative Dehydrogenation/A2 like Self-Coupling and Hydration under Metal-Free Mild Conditions
Source: Wiley
Pd/TiO2-Photocatalyzed Self-Condensation of Primary Amines To Afford Secondary Amines at Ambient Temperature
Source: American Chemical Society (ACS)
Well-Defined Palladium(II)–NHC Precatalysts for Cross-Coupling Reactions of Amides and Esters by Selective N–C/O–C Cleavage
Source: American Chemical Society (ACS)
Visible light-promoted self-coupling of N-chloramines at room temperature: A metal-free access to substituted amides
Source: Taylor & Francis
pH optimization of nucleophilic reactions in water
Source: American Chemical Society (ACS)
Cover Feature: N -Acyl-Glutarimides: Privileged Scaffolds in Amide N-C Bond Cross-Coupling (Eur. J. Org. Chem. 20-21/2018)
Source: Wiley
AIBN-initiated metal free amidation of aldehydes using N-chloroamines
Source: Royal Society of Chemistry (RSC)
Metal-Free Transamidation of Secondary Amides via Selective N–C Cleavage under Mild Conditions
Source: American Chemical Society (ACS)
Metal free access to amide compounds via peroxide-mediated NN double bond cleavage of azobenzenes
Source: Royal Society of Chemistry (RSC)
Aerobic oxidation of secondary benzylic alcohols and direct oxidative amidation of aryl aldehydes promoted by sodium hydride
Source: Elsevier BV
Large-scale manufacture of peptide therapeutics by chemical synthesis
Source: Springer Science and Business Media LLC
Catalytic amide formation from non-activated carboxylic acids and amines
Source: Royal Society of Chemistry (RSC)
Direct One-Pot Synthesis of α-Siloxy-Weinreb Amides from Aldehydes
Source: American Chemical Society (ACS)

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.