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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 50, 2020 - Issue 2
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Synthetic Communications Reviews

Electrochemical decarboxylative sulfonylation of arylacetylenic acids with sodium arylsulfinates: Access to arylacetylenic sulfones

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Pages 161-167 | Received 07 Aug 2019, Published online: 26 Nov 2019
 

Abstract

An efficient decarboxylative sulfonylation of arylacetylenic acids with sodium arylsulfinates has been achieved by an electro-oxidative strategy. This novel protocol offers a simple, efficient, and green route to a series of arylacetylenic sulfones in moderate yields under metal-free and external oxidant-free conditions.

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Additional information

Funding

This work was supported by grants from the National Natural Science Foundation of China [Grant No. 21762022], and the Open Project Program of Polymer Engineering Research Center, Jiangxi Science & Technology Normal University [No. KFGJ19018].

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