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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 50, 2020 - Issue 15
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Articles

Palladium/nickel-mediated cross coupling reaction between phosphorylamides and alkenes toward enephosphorylamides

Zijian ZhaoSchool of Chemistry and Materials Science, Huaihua University, Huaihua, P.R. China; ;College of pharmacy, Shaanxi University of Chinese Medicine, Shaanxi, P. R. China; ;Key Laboratory of Research and Utilization of Ethnomedicinal Plant Resources of Hunan Province, Huaihua University, Huaihua, P. R. ChinaCorrespondence[email protected]
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Qiao ZhuSchool of Chemistry and Materials Science, Huaihua University, Huaihua, P.R. China; ;College of pharmacy, Shaanxi University of Chinese Medicine, Shaanxi, P. R. China; View further author information
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Shiying CheSchool of Chemistry and Materials Science, Huaihua University, Huaihua, P.R. China; View further author information
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Zhenghong LuoSchool of Chemistry and Materials Science, Huaihua University, Huaihua, P.R. China; ;Key Laboratory of Research and Utilization of Ethnomedicinal Plant Resources of Hunan Province, Huaihua University, Huaihua, P. R. ChinaCorrespondence[email protected]
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&
Yan LianSchool of Chemistry and Materials Science, Huaihua University, Huaihua, P.R. China; Correspondence[email protected]
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Pages 2338-2346 | Received 20 Feb 2020, Published online: 16 Jun 2020
 
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Abstract

Enephosphorylamides were herein successfully prepared from phosphorylamides and substituted alkenes. The dehydrogenative transformation took place in the presence of a combination of a palladium diacetate and nickel dichloride. The transition metal-catalyzed methodology enjoyed high efficiency and broad substrate scope. Moreover, a plausible mechanism was proposed for the oxidative C–N cross coupling protocol.

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Funding

The present work was financially supported by the Foundation of Hunan Double First-Rate Discipline Construction Projects [YYZW2018-9 and ZWX2016-11].

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