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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 52, 2022 - Issue 11-12
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Articles

Annulative π-extension of 1-phenylsulfonyl-2/3-bromomethylindole via Zn(OTf)2-mediated domino reaction with thiophene analogs

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Pages 1389-1396 | Received 22 Mar 2022, Published online: 04 Jul 2022
 

Abstract

The reaction of isomeric 2/3-bromomethylindoles containing masked aldehydic function with heteroarenes in the presence of Zn(OTf)2 as a catalyst in 1,2-DCE at room temperature led to the formation of benzo[b]-hetero annulated carbazoles.

Graphical Abstract

Acknowledgements

The authors thank the Department of Science and Technology Funds for the Improvement of Science and Technology (DST-FIST) New Delhi for NMR and HRMS facilities.

Additional information

Funding

The authors graciously acknowledge the Council of Scientific and Industrial Research (CSIR) Project [02(0376)/19/EMR-II] New Delhi for financial support. E. S thanks CSIR, New Delhi for CSIR-SRF fellowship.

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