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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 53, 2023 - Issue 22
113
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Articles

DBU-catalyzed synthesis of unsymmetrical cross-conjugated 2-arylidene-5-((dimethylamino)methylene)cyclopentanones

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Pages 1954-1961 | Received 07 Jul 2023, Published online: 19 Sep 2023
 

Abstract

A simple and efficient method for the synthesis of a new type of unsymmetrical cross-conjugated system based on 2-arylidene-5-((dimethylamino)methylene)cyclopentanone by reaction of 2-arylidenecyclopentanones with dimethylformamide dimethyl acetal catalyzed by DBU was discovered. The preparation of target compounds on a gram-scale is considered. The fluorescent properties of the synthesized systems are considered depending on the structure ofchloroform.

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Disclosure statement

No potential conflict of interest was reported by the author.

Correction Statement

This article has been corrected with minor changes. These changes do not impact the academic content of the article.

Additional information

Funding

The research was carried out within the state assignment of Ministry of Science and Higher Education of the Russian Federation (theme № FSRN-2023-0005).

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