Three-Component Synthesis of Functionalized 1-Azabuta-1,3-dienes from Alkyl Isocyanides, Activated Acetylenes, and Pyridin-2(1H)-one or Isoquinolin-1(2H)-one

Bita Mohtat Chemistry Department, Islamic Azad University, Karaj Branch, Iran

Hoorieh Djahaniani Chemistry Department, Tehran Shargh Branch, Islamic Azad University, Tehran, Iran

Roshanak Khorrami Chemistry Department, Islamic Azad University, Karaj Branch, Iran

Samira Mashayekhi Chemistry Department, Islamic Azad University, Karaj Branch, Iran

Issa Yavari Chemistry Department, Islamic Azad University, Science and Research Branch, Tehran, IranCorrespondence[email protected]

Abstract

The 1:1 reactive intermediates generated by the addition of alkyl isocyanides to dialkyl acetylenedicarboxylates were trapped by pyridin-2(1H)-one and isoquinolin-1(2H)-one to yield highly functionalized 1-azabuta-1,3-dienes and, in some cases, minor amounts of ketenimines.

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Three-Component Synthesis of Functionalized 1-Azabuta-1,3-dienes from Alkyl Isocyanides, Activated Acetylenes, and Pyridin-2(1H)-one or Isoquinolin-1(2H)-one

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Three-Component Synthesis of Functionalized 1-Azabuta-1,3-dienes from Alkyl Isocyanides, Activated Acetylenes, and Pyridin-2(1H)-one or Isoquinolin-1(2H)-one

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