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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 2, 1972 - Issue 5
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Original Articles

Synthetic Methods Based on Sulfonimides I. SN2 Displacement of Ditosylamine

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Pages 297-302 | Received 22 Jun 1972, Published online: 05 Dec 2006
 

Abstract

In organic synthesis oxygen-functionalized carbon compounds (in various oxidation states) are by far the most common intermediates due to their versatility in carbon-carbon bond formation. However in the synthesis of complicated polyfunctional compounds the use of exclusively oxygen-containing functional groups necessitates elaborate schemes of protection and differentiation among these functional groups. Recent syntheses of prostaglandin E1 1 and jasmone2 illustrate the use of nitrogen functions (nitrile, amide, amine, nitro groups) as oxygen equivalents. These successes suggest that additional methods for replacing C-N bonds with C-O should be sought

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