Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 2, 1972 - Issue 1
24
Views
9
CrossRef citations to date
0
Altmetric
Original Articles

Bridged Azibidines. iii. Lead Tetra-Acetae Oxidation of 5-Aminocycloheptene. Synthesis of Dl-2α-Hydroxytrop Ane

, &
Pages 11-19 | Received 15 Dec 1971, Published online: 03 Jan 2007
 

Abstract

5-Aminocycloneptene 3 was oxidized with lead tetraacetate in benzane in the presence of anhydrous potasium carbonate at room tamperature giving the bridged aziridine 4 in ca. 90% yield, this providingand additional example of the new nitrenoid reactionwhich was recently discovered in our laboratory. The aziridine 4 was transformed smoothly intothe 2a-substituted tropanes 13 and 17 and a new synthetic route to these important azacycles was thus established.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.