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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 2, 1972 - Issue 1
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Original Articles

Bridged Aziridines. iv. Lead Tetra-Acetate Oxidation of 6-Aminomethylcyclohepta-1, 3-Diene

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Pages 21-26 | Received 15 Dec 1971, Published online: 03 Jan 2007
 

Abstract

Lead tetra-scetate oxidation of 6-aminomethylcyelohepta-1,3-diene 1 in benzene in the presence of anhydrous potassium carbonate gave the bridged aziridine 8 in good yield, the structural asignment of 8 being confirmed by its ready cleavage with acetic anhydride to the cleavage compound 11.

Lead tetra-scetate oxidation of 6-aminomethylcyelohepta-1,3-diene 1 in benzene in the presence of anhydrous potassium carbonate gave the bridged aziridine 8 in good yield, the structural asignment of 8 being confirmed by its ready cleavage with acetic anhydride to the cleavage compound 11.

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