Benzo- and Indoloquinolizine Derivatives II. Synthesis of 10, 11-Dihydrotribenzo[a, c, h]15bH-Quinolizine

G. Van Binst Vrije Universiteit Brussel, Laboratorium voor Organische Chemie, 105 A. Buyllaan, B 1050, Brussels, Belgium

R. B. Baert Vrije Universiteit Brussel, Laboratorium voor Organische Chemie, 105 A. Buyllaan, B 1050, Brussels, Belgium

R. Salsmans Vrije Universiteit Brussel, Laboratorium voor Organische Chemie, 105 A. Buyllaan, B 1050, Brussels, Belgium

Abstract

We wish to report the synthesis of 10,11-dihydrotribenzo[a, c, h]15bH-quinolizine (4) by photocyclisation of a mixture of 1, 2-diphenyl-3,4-dihydroisoquinoliniumperchlorate (2) and 1,2-diphenylisoquinoliniumperchlorate (3), followed by a sodiumborohydride reduction (Scheme).

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Benzo- and Indoloquinolizine Derivatives II. Synthesis of 10, 11-Dihydrotribenzo[a, c, h]15bH-Quinolizine

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Benzo- and Indoloquinolizine Derivatives II. Synthesis of 10, 11-Dihydrotribenzo[a, c, h]15bH-Quinolizine

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