Synthesis of C-Sulfonylcarbohydroximoyl Chlorides from α-Diazosulfones and Nitrosyl Chloride¹

J. C. Jagt Department of Organic Chemistry, The University, Zernikelaan, Groningen, The Netherlands

Ineke van Buuren Department of Organic Chemistry, The University, Zernikelaan, Groningen, The Netherlands

J. Strating Department of Organic Chemistry, The University, Zernikelaan, Groningen, The Netherlands

A. M. van Leusen Department of Organic Chemistry, The University, Zernikelaan, Groningen, The Netherlands

Abstract

Previous investigations in this laboratory have been concerned with reactions of α-diazosulfones² (1) with electrophilic reagents, such as sulfenyl chlorides², t-butyl hypochlorite^2,3 and halogens⁴, which lead to threefold electronegatively substituted methanes (2). As was anticipated, α-diazosulfones closely resemble α-diazoketones in these reactions.⁵

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Synthesis of C-Sulfonylcarbohydroximoyl Chlorides from α-Diazosulfones and Nitrosyl Chloride¹

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Synthesis of C-Sulfonylcarbohydroximoyl Chlorides from α-Diazosulfones and Nitrosyl Chloride1

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Synthesis of C-Sulfonylcarbohydroximoyl Chlorides from α-Diazosulfones and Nitrosyl Chloride¹